Shin 等报道了一种在低温下制备高分散Zn2SnO4(ZSO) 纳米颗粒的方法,这种纳米颗粒可以用来开发高效柔性的太阳能电池器件。ZSO 纳米颗粒可以在整个可见光范围内有效的提升柔性基体PEN/ITO 的透过率(从75% 提升到90% )。基于ZSO 和CH3NH3PbI3电池的效率达到14.85% 。这一结果证明ZSO 是一种有潜力的用于制备高效柔性太阳能电池的电子传输材料。
Synthesis of ZSO NPs:
All chemicals for the preparation of NPs were of regent grade and were used without further purification. ZnCl2 (12.8 mmol) and SnCl4*5H2O (6.4 mmol) were dissolved in deionized water (160 ml) under vigorous magnetic stirring. N2H4*H2O (N2H4 molar ratio/Zn¼4/1, 8/1, 24/1) was then added to the reaction solution. White precipitates formed immediately, and this solution, including the precipitate, was heated on a hot plate at 90℃ for 12 h. The obtained products were thoroughly washed with deionized water and ethanol and were then dispersed in 2-methoxy ethanol, resulting in a colloidal solution.
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High-performance flexible perovskite solar cells exploiting Zn2SnO4 prepared in solution below 100 ℃
NATURE COMMUNICATIONS | DOI: 10.1038/ncomms8410
Cas | 项目号 | 中文名称 | 规格 |
7646-85-7 | Z820758 | 氯化锌 | 99.95% metals basis |
10026-06-9 | S818286 | 四氯化锡(IV) 五水合物 | 99.995% metals basis |
74-89-5 | M822533 | 甲胺醇溶液 | AR,30-33 wt. % in methanol |
10034-85-2 | H810917 | 氢碘酸 | 55.0-58.0 % |
10035-10-6 | H811364 | 氢溴酸 | 40% |
593-51-1 | M824348 | 甲胺盐酸盐 | 99.5% |
6876-37-5 | M824349 | 甲基溴化胺 | 99.5% |
14965-49-2 | M824044 | 甲基碘化胺 | 99.5% |
6313-33-3 | F824350 | 甲脒盐酸盐 | 99.5% |
146958-06-7 | F824363 | 甲脒氢溴酸盐 | 99.5% |
879643-71-7 | F824046 | 甲脒氢碘酸盐 | 99.5% |
68007-08-9 | I824364 | 咪唑氢碘酸盐 | 99% |
90076-65-6 | B822763 | 双三氟甲烷磺酰亚胺锂 | 99.9% |
207739-72-8 | T822802 | 2,2',7,7'-四[N,N-二(4-甲氧基苯基)氨基]-9,9'-螺二芴(Spiro-MeOTAD) | 99% |
75-05-8 | A801456 | 无水乙腈 | 99.9%,Water≤30 ppm (by K.F.), MkSeal |
108-90-7 | C805820 | 氯苯(CB) | 99%,Water≤50 ppm (by K.F.), MkSeal |
68-12-2 | N807978 | N,N-二甲基甲酰胺(DMF) | 99.8%,Water≤50 ppm (by K.F.),MkSeal |
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