夏海平,1964年生，博士，教授，博士生导师，国家杰出青年基金获得者。厦门大学化学系79级本科生、83级硕士生，硕士毕业后留校任教。

　　主要从事金属有机化学研究。创新性成果有：1）开拓了一系列构筑金属杂环的新方法－－[5+1]、[4+2]和[3+3]关环法；2）将一些经典的有机反应（如SNAr等）拓展到金属有机体系。3）通过引入过渡金属到反芳香性的有机骨架，首次实现了物质从反芳香性到芳香性的一步转变，将芳香性的概念首次拓展到金属杂双五元环体系，同时也首次拓展到一个含三键的五元环体系。开辟了一个全新的芳香体系--金属杂戊搭炔和金属杂戊搭烯化学。该成果入选2013年“中国高校十大科技进展”。

　　已在包括Nat. Chem.、Nat. Commun.、Acc. Chem. Res.、JACS、Angew. Chem.等刊物上发表论文150余篇。通讯作者论文曾被Nature Chemistry、Nature China、美国化学会的C&E News、Heart Cut、Noteworthy Chemistry和英国皇家化学会的Chemistry World等专题评论。Science News网站、俄罗斯化学新闻、国家自然科学基金委网站也曾进行报道。
 

　　近期发表的主要研究论文：
　　55. Zhu, CQ; Yang, YH; Wu, JJ; Luo, M; Fan, JL; Zhu, J; Xia, HP. Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynesby the Reactions of Osmapentalene with Allene, Alkyne, and Alkene. Angew. Chem., Int. Ed. 2015, 54, 7189-7192.

　　54. Wang, TD; Han, FF; Huang, HP; Li, JH; Zhang, H; Zhu, J; Lin, ZY; Xia, HP. Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation Scientific Reports 2015, 5, 9584.

　　53. Wei, YQ; Zhou, XX; Hong, GN; Chen, ZX; Zhang, H; Xia, HP. Reactions of osmapyridinium with terminal alkynes Organic Chemistry Frontiers2015, DOI: 10.1039/C5QO00052A.

　　52. Zhu, CQ; Yang, YH; Luo, M; Yang, Cx; Wu, JJ; Chen, LN; Liu, G; Wen, TB; Zhu, J; Xia, HP. Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics Angew. Chem., Int. Ed. 2015, DOI: 10.1002/anie.201501349.

　　51. Xu, H; Xu, YC; Pang, XC; He, YJ; Jung, JH; Xia, HP; Lin, ZQ. A general route to nanocrystal kebabs periodically assembled on stretched flexible polymer shish Science Advances2015, 1, e1500025.

　　50. Xu, H; Pang, XC; He, YJ; He, M; Jung, JH; Xia, HP; Lin, ZQ. An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic-Inorganic Nanocomposites Angew. Chem., Int. Ed. 2015, 54, 4636-4640.

　　49. Zhu, CQ; Zhou, XX; Xing, HJ; An, K.; Zhu, J; Xia, HP. σ-Aromaticity in an Unsaturated Ring: Osmapentalene Derivatives Containing a Metallacyclopropene Unit.Angew. Chem., Int. Ed. 2015, 54, 3102-3106.

　　48. Han, FF; Li, JH; Zhang, H; Wang, TD; Lin, ZY; Xia, HP. Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene. Chem. Eur. J.2015, 21, 565-567.

　　47. Wang, XR; Zhu, CQ; Xia, HP; Zhu. J, Theoretical Study on the Stability and Aromaticity of Metallasilapentalynes. Organometallics 2014, 33, 1845-1850.

　　46. Han, FF; Wang, TD; Li, JH; Zhang, H; Zhang; LY; He, XM, Xia, HP. Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex. Organometallics 2014, 33, 5301.

　　45. Zhang, H; Lin, R; Li, JH; Xia, HP. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study .Organometallics 2014, 33, 5606.

　　44. Zhou, XX; Zhang, CH; Lin, YM; He, XM; Zhang, Y; Wang, JB, Xia, HP. 1,2-Migration in the reactions of ruthenium vinylcarbene with propargyl alcohols. Org. Chem. Front.2014, 1, 1077.

　　43. Zhu, CQ; Zhu, Q; Fan, JL; Zhu, J; He, XM; Cao, XY, Xia, HP. A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes. Angew.Chem. Int. Ed.2014, 53, 6232.

　　42. Han, FF; Wang, TD; Li, JH; Zhang, H; Xia, HP. m-Metallaphenol: Synthesis and Reactivity Studies. Chem. Eur. J.2014, 20, 4363.(Cover Paper)

　　41. Zhu, CQ; Luo. M; Zhu, Q; Zhu, J; Schleyer,PR; Wu JC; Lu, X; Xia, HP.  Planar M?bius Aromatic Pentalenes Incorporating 16 and 18 Valence Electron Osmiums, Nat. Commun.2014, 5, 3265.

　　40. Cao,XY; Zhao, QY; Lin, ZY; Xia, HP. The Chemistry of Aromatic Osmacycles, Acc. Chem. Res. 2014,47, 341-354.
　　5. Zhu, CQ; Li, SH; Luo. M; Zhou,XX; Niu, YF; Lin, ML; Zhu, J; Cao, ZX; Lu, X; Wen, TB; Xie, ZX; Schleyer,PR; Xia, HP. Stabilizing Antiaromatic and Strained Five-membered Rings by a Transition Metal, Nat. Chem.2013, 5, 698-703. DOI: 10.1038/nchem.1690
　　*德国化学家Uwe Rosenthal教授等在同期《Nature Chemistry》的“News and Views”栏目以《Metallacycles: Breaking the rules》为题撰文评述了这一研究成果（Nat. Chem., 2013, 5, 649-650）。
　　*美国化学会 “Noteworthy Chemistry” 2013年8月5日以“Metallacycles show rare M?bius aromaticity” 为题专题评述这一研究成果。
　　*“Nature China” 2013年8月7日以“Unusual aromatics”为题专题评述这一研究成果。
　　*1981年诺贝尔化学奖获得者、美国康奈尔大学Roald Hoffmann教授在邮件中评价该项工作说：'The paper is an excellent one -- it's quite amazing that the parent Os system, molecule 1, chooses to give the osmapentalyne'，邮件最后说'You can use my name as someone you showed the paper to'。

　　39. Wang, TD；Zhu,J; Han, FF; Zhou,C; Chen,HY; Zhang, H; Xia, HP. Synthesis of Five-Membered Osmacycloallenes and Conversion into Six-Membered Osmacycloallenes, Angew. Chem. Int. Ed.2013, 52(50), 13361-13364.   DOI: 10.1002/anie.201306911

　　38. Niu, YF; Han, FF; Zhang, Q; Xie, TW; Lu, L; Li, SH ; Xia, HP.Off/on fluorescent chemosensors for organotin halides based on binuclear ruthenium complexes,Angew. Chem. Int. Ed. 2013, 52(21), 5599-5603.

　　37. Wang, TD； Zhang, H；Han, FF; Long, LP;Lin, ZY; Xia, HP. Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization,  Angew. Chem. Int. Ed.2013, 52, 9251-9255.  DOI: 10.1002/anie.201302863

　　36. Wang, TD； Zhang, H；Han, FF; Long, LP; Lin, ZY; Xia, HP.cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study, Chem. Eur. J. 2013, 19, 10982 10982 - 10991. DOI: 10.1002/chem.201301398

　　35. Zhang, CH; Zhang, H; Zhang, LY; Wen, TB; He, XM; Xia, HP. Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization，Organometallics2013, 32(13), 3738-3743. DOI: 10.1021/om400372w

　　34. Chen, JX; Zhang, CH; Xie, TW; Wen, TB; Zhang, H; Xia, HP.Conversion of Complex to h2-Allene-coordinated Complexes and Metallabenzenes, Organometallics 2013, 32(14), 3993-4001.

　　33. Hong, GN; Zhang, H; Lin, YJ; Chen, YJ; Xu, YZ; Weng, WG Xia, HP. Mechanoresponsive Healable Metallosupramolecular Polymers, Macromolecules 2013, 46, 8649?8656.

　　32. Zhao, QY; Cao,XY; Wen,TB; Xia, HP. From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates Chem. Asian J. 2013, 8, 269-275.

　　31. Zhu, CQ; Cao, XY; Xia, HP. Double Stabilization of Highly Strained Six-Membered Rings by Phosphonium and Transition Metal, Chin. J. Org. Chem.2013, 33, 657- 662.（Invited and Cover Paper)

　　30. Liu, B; Zhao, QY; Wang HJ; Zeng BR; Cao, XY; Xia, HP. Reactivity study of a hydroxyl coordinated osmium vinyl complex OsCl2(PPh3)2[CH=C(PPh3)CHPh(OH)], Sci. China Chem., 2013，56 (8), 1105-1111;  doi: 10.1007/s11426-013-4876-y（Invited Paper)

　　29. 张春红;张弘;魏爱琳;何旭敏; 夏海平. 由钌杂s-顺丁二烯化合物合成钌杂多环配合物的研究, Acta Chim. Sinica(化学学报),2013, 71, 1373-1378. （Invited and Cover Paper)

　　28. Wang, TD； Zhang, H；Han, FF, Lin, R; Lin, ZY, Xia, HP;Synthesis and Characterization of a Metallapyridyne Complex, Angew. Chem. Int. Ed.2012,51, 9838-9841.

　　27. Zhao, QY; Zhu, J; Huang, ZA; Cao, XY; Xia, HP; Conversions of Osmabenzyne and Isoosmabenzene , Chem. Eur. J.2012, 18, 11597-11603.

　　26.  Lin, R; Zhao, J; Chen, HY; Zhang, H; Xia, HP., Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes, Chem. Asian J. 2012, 7, 1915-1924.

　　25. Zhao, QY; Gong, L; Xu, CF; Zhu, J; He, XM; Xia, HP. Stable Isoosmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols, Angew. Chem. Int. Ed.2011, 50, 1354 - 1358.

　　24. Lin, R; Zhang, H; Li, SH; Wang, J; Xia, HP. New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction, Chem. Eur. J.2011, 17, 4223-4231. (Inside Cover)

　　23. Lin, R; Zhang, H; Li, SH; Chen, LQ; Zhang, WG; Wen, TB; Zhang, H; Xia, HP. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with l- and d-Cysteine, Chem. Eur. J.2011, 17, 2420 - 2427. 2011年2月28日美国化学会网页“Noteworthy Chemistry”栏目针对本文发表点评。

　　22. Zhang, H; Lin, R; Hong, GN; Wang, TD; Wen, TB; Xia, HP. Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes, Chem. Eur. J.2010, 16, 6999 - 7007.

　　21. Yu, ZJ; Huang, MH; Fang, YF; Li, R; Zhan, JY; Zeng, BR; He, GM; Xia, HP, Zhang, LT. Modification of a Liquid Polycarbosilane with 9-BBN as a High-ceramic-yield Precursor for SiC，Reactive & Functional Polymers2010, 70, 334-339.

　　20. Yu, ZJ； Zhan, J； Huang, MH; Li, R; Zhou, C; He, GM; Xia, HP, Preparation of a Hyperbranched Polycarbosilane Precursor to SiC Ceramics Following an Efficient Room-temperature Cross-linking Process, J. Mater. Sci.2010, 45, 6151-6158.

　　19. Huang, JB; Lin, R; Wu, LQ; Zhao, QY; Zhu, CQ; Wen, TB; Xia, HP. Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides, Organometallics2010, 29, 2916-2925.

　　18. Lin, YM; Xu, H; Gong, L; Wen, TB; He, XM;Xia, HP. C-H Bond Activation and Subsequent C(sp2)-C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex, Organometallics2010, 29, 2904-2910.

　　17. He, XM; Gong, L; Kraling, K; Grundler, K; Frias, C; Webster, R. D.; Meggers, E; Prokop, A; Xia, HP. Unusual h2-Allene Osmacycle with Apoptotic Properties, ChemBioChem2010, 11, 1607-1613.

　　16. Wang, TD; Li, SH; Zhang H; Lin R; Han FF; Lin YM; Wen TB; Xia, HP. Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48(35), 6453-6456.

　　15. Liu, B; Wang, HJ; Xie, HJ; Zeng, BR; Chen, JX; Tao, J; Wen, TB; Cao; ZX, Xia, HP. Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction, Angew. Chem. Int. Ed.（VIP）2009, 48(30), 5430-5434. 本文为该杂志的VIP（Very Important Paper）和 Frontispiece Paper。英国皇家化学会的“Chemistry Word”2009年4月14日针对本文发表了题为“锇和吡啶环在一起”的报道。文章首句写到：中国有机化学家发现了一种把金属锇放到吡啶环中的方法。该报道被多家韩、俄文科技媒体转载。

　　14. Liu B; Xie HJ; Wang HJ; Wu LQ; Zhao QY; Chen JX; Wen, TB; Cao ZX; Xia, HP. Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular C-H Activation, Angew. Chem. Int. Ed. 2009, 48(30), 5461-5464.

　　13. Gong, L; Chen, ZN; Lin, YM; He, XM; Wen, TB; Xu, X; Xia, HP.Osmabenzenes from Osmacycles Containing an h2-Coordinated Olefin, Chem. Eur. J.2009, 15(25), 6258-6266.

　　12. Zhang, H; Wu, LQ; Lin, R; Zhao, QY; He, GM; Yang, FZ; Wen, TB; Xia, HP. Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents, Chem. Eur. J. 2009, 15(14), 3546-3559.

　　11. Gong, L; Lin, YM; Wen, TB; Xia, HP. Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-coordinated Alkyne Alcohol Complex, Organometallics 2009, 28, 1101-1111.

　　10. Lin, YM; Gong, L; Xu, H; He, XM; Wen, TB; Xia, HP. Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran, Organometallics 2009, 28, 1524-1533.

　　9. Gong, L; Lin, YM; Wen, TB; Zhang, H; Zeng, BR; Xia, HP. Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction，Organometallics, 2008, 27, 2584-2589.

　　8. Gong, L; Lin, YM; He, GM; Zhang, H; Wang, HJ; Wen, TB; Xia, HP. Synthesis and characterization of an air-stable p-osmaphenol, Organometallics, 2008, 27(3), 309-311.

　　7. Wu, LQ; Feng, L; Zhang, H; Liu, QX; He, XM; Yang, FZ; Xia, HP. Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride, J. Org. Chem.2008, 73, 2883-2885.

　　6. Fang, YH; Huang, MH; Yu, ZJ; Xia, HP; Chen, LF; Zhang, Y; Zhang, LT. Synthesis, Characterization, and Pyrolytic Conversion of a Novel Liquid Polycarbosilane，J. Am. Ceram. Soc.2008, 91(10), 3298-3302.

　　5. Zhang, H; Feng, L; Gong, L; Wu, LQ; He, GM; Wen, TB; Yang, FZ; Xia, HP. Synthesis and characterization of stable ruthenabenzenes starting from HC?CCH(OH)C?CH, Organometallics, 2007, 26(10), 2705-2713

　　4. Gong, L; Wu, LQ; Lin, YM; Zhang, H; Yang, FZ; Wen, TB; Xia, HP. Synthesis and characterization of a bimetallic iridium complex with a bridge of ten sp2-carbon chain，Dalton Trans.2007, 37, 4122-4125. (Hot Article)

　　3. Zhang, H; Xia, HP; He, GM; Wen, TB; Jia, GC. Synthesis and characterization of stable ruthenabenzenes, Angew. Chem. Int. Ed.（VIP）2006, 45(18), 2920-2923. 本文为该杂志的“VIP（Very Important Paper）”。美国化学会网页“Heart Cut” 栏目2006年5月30日针对本文发表题为 “现在你可以制备稳定的钌苯了”的评论。

　　2. Xia, HP; He, GM; Zhang, H; Wen, TB; Sung, HHY; Williams, ID; Jia, GC. Osmabenzenes from the reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br), J. Am. Chem. Soc. 2004, 126(22), 6862-6863. 美国化学会的“Chemical & Engineering News”, 82(23), 30（2004年6月7日）针对本文发表题为“锇苯很容易做”的报道。
 

　　1. 何国梅、夏海平、贾国成,“金属苯”的合成及反应性的研究进展，科学通报，2004, 49(11), 1020-1030。

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