张文雄
1.教育和工作经历:
2009.10 ~ 2009.12, 日本理化学研究所客座研究员
2007.10, 北京大学化学学院副教授
2004.11-2007.9, 日本理化学研究所协力研究员
2004.1-2004.3, 日本北海道大学JST研究员
2002.10-2004.10, 北京大学化学学院博士后
2003.1, 获南开大学理学博士学位
1999.6, 获广西师范大学理学硕士学位
1996.7,获湖南师范大学化学教育学士学位
2.研究领域和兴趣:
稀土金属有机簇合物的设计、合成及反应性研究;金属催化或促进的有机合成化学及通过从反应体系中分离、表征活性中间体对反应机理进行研究。在研究过程中,我们力求把导向有机合成的金属有机化学(OMCOS)和经典的金属有机化学(OM)结合起来,不仅注重新反应的发现和发展,更注重于通过对反应机理的理解和认识,有目的地发现新反应。
3.代表性论文
Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi.* "Zirconocene and Si-tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis". Acc. Chem. Res. 2011, 44, ASAP(ar-2011-00078e).
Yang Wang, Wen-Xiong Zhang,* Zitao Wang, and Zhenfeng Xi.* "Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and Their Selenium and Tellurium Derivatives by Convergent Tandem Annulation".Angew. Chem. Int. Ed. 2011, 50, ASAP(anie.201101948).
Wen-Xiong Zhang, Zitao Wang, Masayoshi Nishiura, Zhenfeng Xi,* and Zhaomin Hou.* "Ln4(CH2)4-Cubane-Type Rare-Earth Methylidene Complexes Consisting of “(C5Me4SiMe3)LnCH2” Units (Ln = Tm, Lu)". J. Am. Chem. Soc. 2011, 133, 5712-5715. (Highlighted by Riken Research)
Zitao Wang, Yang Wang, Wen-Xiong Zhang,* Zhaomin Hou, and Zhenfeng Xi.* "Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur and Carbodiimides". J. Am. Chem. Soc. 2009, 131, 15108–15109.
Wen-Xiong Zhang, Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou,* and Zhenfeng Xi.* "Isolation and Application of Unpredicted Three-ring-fused Zr/Si Intermediates in Zirconocene-mediated Intermolecular Coupling Reaction". Angew. Chem. Int. Ed. 2009, 48, 7227–7231.
Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou.* "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes". Angew. Chem. Int. Ed. 2008, 47, 9700-9703. (Highlighted by Synfacts and Riken Research)
Wen-Xiong Zhang, Masayoshi Nishiura, and Zhaomin Hou.* "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes".J. Am. Chem. Soc. 2005, 127, 16788-16789.
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